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PVDF Binder for Battery

Item No.: XW-PVDF-770
Application: This XW-PVDF-770 PVDF binder is especially suitable for high-nickel materials and sodium-ion batteries. It can solve the gel problem when mixing the slurry. In addition, it can also soften the battery electrode.
Warranty: One Year warranty with lifetime support;
Order(MOQ): 1 set;
Payment: T/T,Western Union, Paypal,L/C;
Product Origin: China;
Lead Time: in stock or 1-10days,ect;
Note: XIAOWEI factory supports OEM.

 Products Description 

XW-PVDF-770 Binder for Lithium-ion and Sodium-ion Batteries

Feature

XW-PVDF-770 is a high-performance fluoropolymer binder specifically designed for use in lithium-ion and sodium-ion battery electrodes.

It is particularly suitable for high-nickel cathode materials (such as NMC811, NCA) and sodium-ion batteries. The binder effectively solves common issues such as slurry gelation during the mixing process and enhances electrode flexibility by softening the electrode structure.

Compared with conventional PVDF binders, XW-PVDF-770 exhibits superior alkali resistance, ensuring long-term stability when used with strong alkaline active materials. This enables stable and reliable electrode coating during manufacturing.

In addition, the binder provides excellent flexibility, enabling high electrode density and contributing to increased battery capacity and enhanced overall battery performance.

Properties of PVDF in Battery Applications

  1. Binder Function
    PVDF acts as a binder to adhere the active material (e.g., LiCoO₂, LiFePO₄ for cathodes or graphite for anodes) and the conductive additive (e.g., carbon black) to the current collector (aluminum foil or copper foil), maintaining electrode integrity and preventing material detachment during charge/discharge cycles.
  2. Chemical Stability
    PVDF demonstrates outstanding chemical inertness in battery electrolytes, offering excellent corrosion resistance and contributing to longer battery life.
  3. Mechanical Strength
    PVDF provides sufficient mechanical strength to withstand the volume changes of electrode materials during cycling, reducing the risk of cracking and delamination.
  4. Thermal Stability
    The high thermal resistance of PVDF ensures structural stability in elevated temperature environments, thereby enhancing battery safety.
  5. Ionic Conductivity
    While PVDF itself is not inherently conductive, its ionic conductivity can be improved by incorporating plasticizers or blending with other materials, optimizing overall battery performance.

Application in Battery Research and Manufacturing

Electrode Preparation
PVDF is widely used as a binder in electrode fabrication. It is mixed with active materials and conductive agents to form a slurry, which is then coated onto the current collector. After drying and calendering, a uniform electrode sheet is produced.

Battery Performance Optimization
By adjusting the molecular weight, concentration, and processing parameters of PVDF, manufacturers can optimize the bonding strength, mechanical properties, and conductivity of electrodes to enhance battery performance.

New Battery Development
PVDF is also applied in advanced battery systems such as solid-state batteries and lithium-sulfur batteries, serving as a binder or polymer matrix, supporting innovation and next-generation battery technology.

 Technical Parameters

Properties Typical Value Test method
Physical
Specific Gravity 1.76 – 1.79 ASTM D792
Molecular Weight※1 1.5- 2.0×106 GPC
Water Absorption※2 <0.2% ASTM D543
Mechanical
Tensile Modulus※3 600 to 800 MPa ASTM D638
Viscosity
Solution Viscosity※4 1140 to 2250 mPa・s B-type viscometer
Intrinsic Viscosity※5 0.25 to 0.32 l/g Ubbelohde viscometer
Thermal
Melting Point※6 163 to 173oC DSC
Glass Transition Temperature※7 -30 to -40oC DSC
Heat of Fusion※7 45 to 55 J/g DSC
Peak Crystallization Temperature※8 135 to 145oC DSC
Thermal Stability※9 >370oC TGA
Electrical
Surface Resistivity※10 >1.0E+14 ohms JIS K6911
Volume Resistivity※10 >1.0E+14 ohms・cm JIS K6911
Weight loss on heat
Volatile※11 0.1 wt% MAX Daikin’s method
※1. Molecular weight data were obtained by Gel permeation Chromatography in dimethylformamide. (40℃)
※2. 23 ℃, 24hr
※3. The test sample is a press sheet at 250℃.   Thickness: 2 mm , Dumbbell TypeⅣ, Speed: 50mm/min
※4. B-type viscometer, Rotor no.THM-13, 12rpm, 25 ℃
※5. DMF, 30 ℃, Ubbelohde viscometer
※6. Heating rate: 20℃/min, Main peak
※7. Heating rate: 20℃/min
※8. Cooling rate: 20℃/min, Main peak
※9. @ 1% weight loss
※10. Film thickness: 35 mm, After 5 min, 500V @23℃, 30%RH
※11. Weight loss after heating for 2 hours at 150℃
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